A more realistic fuel consumption for the Civic EHev is 5.5 lt/100 km (45 miles/US gallon, 55 miles/UK gallon). This would be for 50% city and 50% highway.
To get the best fuel economy go easy on the accelerator and keep speeds on the highway at 110 km/hr (70 miles/hr) or less. Fuel economy drops like a rock over 120 km/hr (75 mph),
Non-hybrids do almost the same fuel economy on the highway as hybrids
do. Hybrids get MUCH better fuel economy in urban driving than non-hybrids do because they just use battery power at lower speeds. The ideal customer for a hybrid is someone who spends more than 50% of their driving in urban environments.
Judging by your stated use, you are far from the ideal customer for a hybrid. If I was doing 80% highway driving I would have bought a non-hybrid car.
Watch this video.
Driving the EHev Civic as economically as possible.
Caveat on this, as I discovered with a 2020 CR-V Hybrid: the first 10 minutes or so of driving, even in "urban environments", is typically going to be using the ICE engine as the battery warms up. So you need to be doing urban driving that is longer than 10 minutes from a cold start.
A 30 minute trip in the city got terrific fuel economy, but in general daily use over the course of a year (across four seasons) I got about 34 MPG (US), which wasn't enough to offset the lack of oomph over 60 MPH in that car.
I'll take the 30-ish MPG that I get with my 2022 Civic ST with the 1.5T engine. Given that I drive about 7500 miles per year in my car, the difference would amount to 30 gallons a year, which is not a big deal. And having a 6MT is more fun for me, too (usually).
On the other hand, I'm very curious about the new 2025 Civic ST Hatchback Hybrid, as it seems to be much better performing than that 2020 CR-V Hybrid on the top end (I've passed it on to my daughter).
But if the hybrid benefit in fuel economy is still like the CR-V Hybrid was (that I would need to drive for 10 minutes before I start to see real benefit from the battery), I would be more inclined to just stay with the car I've already got, until I have a better reason to move to another car. Most of my local driving is in the 15-20 minute trip range.